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- W2899249903 endingPage "7043" @default.
- W2899249903 startingPage "7039" @default.
- W2899249903 abstract "The gold(I)-catalyzed enantioselective hydroetherification of alkynes was achieved via desymmetrization of prochiral bisphenols bearing P-stereogenic centers. ( S)-DTBM-Segphos(AuCl)2/AgNTf2 proved to be a highly efficient catalyst system for this transformation, affording P-chiral cyclic phosphine oxides in good yields with high enantioselectivities (with up to 99% ee). The same catalyst system allowed for the enantioselective desymmetrization of dialkynes. Synthetic transformations of the cyclization products afforded other P-chiral molecules with high enantiospecificity." @default.
- W2899249903 created "2018-11-09" @default.
- W2899249903 creator A5025329094 @default.
- W2899249903 creator A5040782314 @default.
- W2899249903 creator A5075661875 @default.
- W2899249903 date "2018-10-29" @default.
- W2899249903 modified "2023-10-10" @default.
- W2899249903 title "Enantioselective and Regioselective Hydroetherification of Alkynes by Gold-Catalyzed Desymmetrization of Prochiral Phenols with P-Stereogenic Centers" @default.
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- W2899249903 doi "https://doi.org/10.1021/acs.orglett.8b02982" @default.
- W2899249903 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30371092" @default.
- W2899249903 hasPublicationYear "2018" @default.
- W2899249903 type Work @default.