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• W2899304734 abstract "Four different Lewis acids that might participate in a tetrel bond with a nucleophile (SEt2Me+, NMe4+, SMe2, NMe3) are examined. The NMR chemical shifts of the methyl C and H atoms are calculated as the CH bond lengths are systematically stretched and contracted, in the absence of a base. The C shielding diminishes by roughly 2 ppm for a stretch of 0.01 Å, while that of H drops by only 0.3 ppm. The deshieldings caused purely by the bond length changes are far too small to account for the amounts that are computed when the nucleophile is actually present." @default.
• W2899304734 created "2018-11-09" @default.
• W2899304734 creator A5085422555 @default.
• W2899304734 date "2019-01-01" @default.
• W2899304734 modified "2023-09-26" @default.
• W2899304734 title "Dependence of NMR chemical shifts upon CH bond lengths of a methyl group involved in a tetrel bond" @default.
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• W2899304734 doi "https://doi.org/10.1016/j.cplett.2018.10.069" @default.
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