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- W2899366942 abstract "An efficient method for the enantio- and diastereoselective construction of multisubstituted tetrahydrofurans via asymmetric decarboxylative cycloaddition of vinylethylene carbonates with β-nitroolefins under a cooperative catalysis of palladium complex and squaramide is developed. By using a palladium complex generated in situ from Pd2(dba)3·CHCl3 and phosphoramidite L1 and chiral squaramide OC4 as cooperative catalysts under mild conditions, the process provided multisubstituted tetrahydrofurans bearing a quaternary stereocenter in good to high yields with acceptably high enantio- and diastereoselectivities." @default.
- W2899366942 created "2018-11-09" @default.
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- W2899366942 date "2018-11-02" @default.
- W2899366942 modified "2023-10-16" @default.
- W2899366942 title "Asymmetric Decarboxylative Cycloaddition of Vinylethylene Carbonates with β-Nitroolefins by Cooperative Catalysis of Palladium Complex and Squaramide" @default.
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- W2899366942 doi "https://doi.org/10.1021/acscatal.8b03582" @default.
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