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• W2899402241 abstract "The local chemical activation of surface-anchored metal–organic frameworks is a novel electron beam-based lithographic technique with a high potential for the fabrication of chemically and spatially well-defined nanostructures in the sub-10 nm regime. In this context, we have performed a detailed investigation of electron beam-induced surface activation (EBISA) on the surface-anchored layers of HKUST-1 and copper(II) oxalate with the subsequent autocatalytic growth (AG) of deposits from the precursors Fe(CO)5 and Co(CO)3NO. We use reflection absorption infrared spectroscopy and measurements on electron-stimulated desorption to identify the chemical species that trigger decomposition of the precursors on the activated surfaces. EBISA on HKUST-1 works for Fe(CO)5 but not for Co(CO)3NO and is therefore chemical selective. On the other hand, we demonstrate that copper(II) oxalate is not susceptible to EBISA for both precursors, ruling out that Cu nanoparticles are active sites for initiating AG. A detailed discussion and comparison of the experimental results for both substrates and precursors is supported by a review of the current state of knowledge regarding the electron-induced chemistry of the investigated materials and on the precursor reactivity. On the basis of this analysis, we discuss specific species that are likely to trigger AG following EBISA of HKUST-1." @default.
• W2899402241 created "2018-11-09" @default.
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• W2899402241 date "2018-10-31" @default.
• W2899402241 modified "2023-10-17" @default.
• W2899402241 title "Electron Beam-Induced Surface Activation of Metal–Organic Framework HKUST-1: Unraveling the Underlying Chemistry" @default.
• W2899402241 cites W167788655 @default.
• W2899402241 cites W1963547259 @default.
• W2899402241 cites W1971596937 @default.
• W2899402241 cites W1973381743 @default.
• W2899402241 cites W1975246736 @default.
• W2899402241 cites W1976180897 @default.
• W2899402241 cites W1978276690 @default.
• W2899402241 cites W1985249245 @default.
• W2899402241 cites W1987726060 @default.
• W2899402241 cites W1994171065 @default.
• W2899402241 cites W1998041021 @default.
• W2899402241 cites W1998151715 @default.
• W2899402241 cites W2001437318 @default.
• W2899402241 cites W2002928929 @default.
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• W2899402241 cites W2006850536 @default.
• W2899402241 cites W2007439897 @default.
• W2899402241 cites W2009441536 @default.
• W2899402241 cites W2011549700 @default.
• W2899402241 cites W2013246656 @default.
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• W2899402241 cites W2022938210 @default.
• W2899402241 cites W2026270074 @default.
• W2899402241 cites W2031696446 @default.
• W2899402241 cites W2034864816 @default.
• W2899402241 cites W2035733716 @default.
• W2899402241 cites W2035743230 @default.
• W2899402241 cites W2036865567 @default.
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• W2899402241 doi "https://doi.org/10.1021/acs.jpcc.8b06226" @default.
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