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• W2899424478 endingPage "1831" @default.
• W2899424478 startingPage "1826" @default.
• W2899424478 abstract "We herein investigated the synthesis of the Ce 4+ ‐based metal‐organic framework [Ce 6 (μ 3 ‐O) 4 (μ 3 ‐OH) 4 (PZDC) 4 (OH) 4 (H 2 O) 4 ] denoted as Ce‐DUT‐67‐PZDC (where DUT stands for Dresden University of Technology and PZDC 2– stands for 3,5‐pyrazoledicarboxylate) by in‐situ powder X‐ray diffraction methods under solvothermal conditions using synchrotron radiation. It was observed that the obtained MOF is rapidly formed between 120 and 140 °C, but only as an intermediate product in this preparative system. After prolonged reaction times, Ce 4+ is reduced to Ce 3+ and reacting with formic acid from the reaction mixture to form the final product [Ce(O 2 CH) 3 ]. During the formation of trivalent cerium formate, the Ce(IV)‐MOF completely re‐dissolves. Based on the composition of the reaction mixture and the recorded data, a plausible reaction mechanism was established. This mechanistic scheme includes a reversible precipitation of the Ce(IV)‐MOF under the given conditions and the reduction of Ce 4+ by formate anions generated via hydrolysis of the solvent dimethylformamide." @default.
• W2899424478 created "2018-11-09" @default.
• W2899424478 creator A5003915615 @default.
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• W2899424478 date "2018-10-31" @default.
• W2899424478 modified "2023-09-25" @default.
• W2899424478 title "Investigation of the Kinetic Stabilization of a Ce⁴⁺ -based MOF by in-situ Powder X-ray Diffraction" @default.
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• W2899424478 doi "https://doi.org/10.1002/zaac.201800354" @default.
• W2899424478 hasPublicationYear "2018" @default.
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