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- W2899428141 abstract "Abstract The reaction of readily generated silyl lithium reagents with various aryl fluorides to provide the corresponding aryl silanes is reported. DFT calculations reveal that the nucleophilic aromatic substitution of the fluoride anion by the silyl lithium reagent proceeds through concerted ipso substitution. In contrast to the classical nucleophilic aromatic substitution, this concerted ionic silyldefluorination also occurs on more electron‐rich aryl fluorides." @default.
- W2899428141 created "2018-11-09" @default.
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- W2899428141 date "2018-12-03" @default.
- W2899428141 modified "2023-10-12" @default.
- W2899428141 title "Silyldefluorination of Fluoroarenes by Concerted Nucleophilic Aromatic Substitution" @default.
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- W2899428141 doi "https://doi.org/10.1002/anie.201808646" @default.
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