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- W2899444895 abstract "Interfacial properties of oligomeric molecules play an important role in emulsion polymerization. The radicals generated from water soluble initiators react with monomers in the aqueous phase until the oligomers become sufficiently hydrophobic to partition into the polymer particle phase and carry out the intended further chain propagation. Before reaching the critical composition and molecular weight when oligomers become effectively trapped in the particles, radicals may enter and exit particles readily via diffusion. Better tools and techniques are needed to understand the aqueous phase chemistry and interfacial behavior of aqueous oligomers. In this study, a model emulsion polymerization system was used to generate oligomers with various compositions and chain lengths. Formation of aqueous phase oligomers, as well as the reaction pathways in the early stage of emulsion polymerization, were revealed by LC-MS analysis. Partition coefficients (Log D) of the aqueous oligomers were determined using an LC-MS method to evaluate the amphiphilicity of molecules. It was demonstrated that the composition and amount of aqueous phase oligomers are restricted by their Log D." @default.
- W2899444895 created "2018-11-09" @default.
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- W2899444895 date "2018-01-01" @default.
- W2899444895 modified "2023-09-26" @default.
- W2899444895 title "Identification of Aqueous Phase Oligomers Formed during Emulsion Polymerization and Their Interfacial Behavior via LC-MS" @default.
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- W2899444895 doi "https://doi.org/10.1021/bk-2018-1281.ch005" @default.
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