FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2899458506> ?p ?o ?g. }

• W2899458506 endingPage "2785" @default.
• W2899458506 startingPage "2773" @default.
• W2899458506 abstract "Abstract Three amide ligands of varying steric bulk and electronic properties were utilized to prepare a series of amido‐germanium(II)/tin(II) halide compounds, (LEX) n , (L= ‐N{B(DipNCH) 2 }(SiMe 3 ), TBo L; ‐N{B(DipNCH) 2 }(SiPh 3 ), PhBo L; ‐N(Dip)( t Bu), DBu L; Dip=C 6 H 3 i Pr 2 ‐2,6; E=Ge or Sn; X=Cl or Br; n =1 or 2). Reductions of these with a magnesium(I) dimer, {( Mes Nacnac)Mg} 2 ( Mes Nacnac=[(MesNCMe) 2 CH] − , Mes=mesityl), afforded singly bonded amido‐digermynes ( TBo LGe−Ge TBo L and PhBo LGe−Ge PhBo L), and an amido‐distannyne ( PhBo LSn−Sn PhBo L), in addition to several low‐valent, amido stabilized tetrel–tetrel bonded cluster compounds, ( DBu LGe) 4 , ( DBu LSn) 6 and Sn 5 ( TBo L) 4 . The nature of the products resulting from these reactions was largely dependent on the steric bulk of the amide ligand employed. Cluster ( DBu LGe) 4 possessed an unusual folded butterfly structure, the bonding and electronic of which were examined using DFT calculations. Reactions of the amido‐germanium(I) compounds with H 2 were explored, and gave rise to the amido‐digermene, TBo L(H)Ge=Ge(H) TBo L and the cyclotetragermane, { DBu L(H)Ge} 4 . Reactions of ( DBu LGe) 4 with a series of unsaturated small molecule substrates yielded DBu LGeOGe DBu L, DBu LGe(μ‐C 2 H 4 ) 2 Ge DBu L and DBu LGe(μ‐1,4‐C 6 H 8 )(μ‐1,2‐C 6 H 8 )Ge DBu L. The latter results imply that ( DBu LGe) 4 can act as a masked source of the digermyne DBu LGeGe DBu L in these reactions. All further reactivity studies indicated that the germanium(I) compounds exhibit a “transition‐metal‐like” behavior, which is closely related to that previously described for bulky digermynes and related compounds." @default.
• W2899458506 created "2018-11-09" @default.
• W2899458506 creator A5003309718 @default.
• W2899458506 creator A5009883474 @default.
• W2899458506 creator A5015779135 @default.
• W2899458506 creator A5023029594 @default.
• W2899458506 creator A5033413160 @default.
• W2899458506 creator A5087456866 @default.
• W2899458506 date "2018-12-13" @default.
• W2899458506 modified "2023-10-18" @default.
• W2899458506 title "Synthesis and Reactivity Studies of Amido‐Substituted Germanium(I)/Tin(I) Dimers and Clusters" @default.
• W2899458506 cites W1799576023 @default.
• W2899458506 cites W1965206452 @default.
• W2899458506 cites W1966690187 @default.
• W2899458506 cites W1967266229 @default.
• W2899458506 cites W1971318685 @default.
• W2899458506 cites W1971428915 @default.
• W2899458506 cites W1972274370 @default.
• W2899458506 cites W1974119499 @default.
• W2899458506 cites W1981370513 @default.
• W2899458506 cites W1984348005 @default.
• W2899458506 cites W1987014825 @default.
• W2899458506 cites W1995518375 @default.
• W2899458506 cites W2000840258 @default.
• W2899458506 cites W2002611928 @default.
• W2899458506 cites W2007009327 @default.
• W2899458506 cites W2010269102 @default.
• W2899458506 cites W2013803125 @default.
• W2899458506 cites W2016950685 @default.
• W2899458506 cites W2018330201 @default.
• W2899458506 cites W2019851030 @default.
• W2899458506 cites W2021468752 @default.
• W2899458506 cites W2043706076 @default.
• W2899458506 cites W2047877837 @default.
• W2899458506 cites W2053609112 @default.
• W2899458506 cites W2055757267 @default.
• W2899458506 cites W2057836976 @default.
• W2899458506 cites W2060013781 @default.
• W2899458506 cites W2060732591 @default.
• W2899458506 cites W2064674762 @default.
• W2899458506 cites W2066607597 @default.
• W2899458506 cites W2071161979 @default.
• W2899458506 cites W2096005073 @default.
• W2899458506 cites W2101611891 @default.
• W2899458506 cites W2104587737 @default.
• W2899458506 cites W2110035145 @default.
• W2899458506 cites W2115499738 @default.
• W2899458506 cites W2126396516 @default.
• W2899458506 cites W2133779642 @default.
• W2899458506 cites W2136005079 @default.
• W2899458506 cites W2142953993 @default.
• W2899458506 cites W2165170376 @default.
• W2899458506 cites W2165657841 @default.
• W2899458506 cites W2170090446 @default.
• W2899458506 cites W2194248402 @default.
• W2899458506 cites W2236616254 @default.
• W2899458506 cites W2317988585 @default.
• W2899458506 cites W2320365484 @default.
• W2899458506 cites W2321607249 @default.
• W2899458506 cites W2326947866 @default.
• W2899458506 cites W2332950207 @default.
• W2899458506 cites W2333541509 @default.
• W2899458506 cites W2334797796 @default.
• W2899458506 cites W2462152538 @default.
• W2899458506 cites W2566630193 @default.
• W2899458506 cites W2582824092 @default.
• W2899458506 cites W2738667317 @default.
• W2899458506 cites W2745336929 @default.
• W2899458506 cites W2757898145 @default.
• W2899458506 cites W2783029725 @default.
• W2899458506 cites W2791359566 @default.
• W2899458506 cites W2802666798 @default.
• W2899458506 cites W2809207845 @default.
• W2899458506 cites W2883754955 @default.
• W2899458506 cites W2892104602 @default.
• W2899458506 cites W2952195305 @default.
• W2899458506 cites W4206278248 @default.
• W2899458506 cites W4230113892 @default.
• W2899458506 cites W4243023626 @default.
• W2899458506 cites W4252738261 @default.
• W2899458506 cites W4253244666 @default.
• W2899458506 doi "https://doi.org/10.1002/chem.201804770" @default.
• W2899458506 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30370947" @default.
• W2899458506 hasPublicationYear "2018" @default.
• W2899458506 type Work @default.
• W2899458506 sameAs 2899458506 @default.
• W2899458506 citedByCount "41" @default.
• W2899458506 countsByYear W28994585062019 @default.
• W2899458506 countsByYear W28994585062020 @default.
• W2899458506 countsByYear W28994585062021 @default.
• W2899458506 countsByYear W28994585062022 @default.
• W2899458506 countsByYear W28994585062023 @default.
• W2899458506 crossrefType "journal-article" @default.
• W2899458506 hasAuthorship W2899458506A5003309718 @default.
• W2899458506 hasAuthorship W2899458506A5009883474 @default.
• W2899458506 hasAuthorship W2899458506A5015779135 @default.
• W2899458506 hasAuthorship W2899458506A5023029594 @default.
• W2899458506 hasAuthorship W2899458506A5033413160 @default.

• next