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- W2899486145 abstract "Two fusion methods were established for rapid determination of Pu in soil and sediment samples. The methods consisted of NH4HSO4 or NH4HF2 fusion procedures incorporated with procedures for CaF2/LaF3 co-precipitation, extraction chromatography and SF-ICP-MS measurement. The fusion procedures were done on a portable hot plate instead of in a cumbersome muffle furnace and took only 15 min heating-up time from room temperature to 250 °C and 15 min fusion time at 250 °C. Chemical recoveries of Pu after completing the NH4HSO4 and NH4HF2 fusion methods for 0.5-1 g sample were approximately 70% and more than 90%, respectively, and decreased with the increase of sample weight from 0.5 g to 5 g. Sediment samples were pre-ignited at different temperatures ranging from 450 °C to 1000 °C to form refractory fractions of Pu, with which the dissolution rates of Pu by the NH4HSO4 and NH4HF2 fusion were investigated. With the increase of pre-ignition temperature of the sediment samples, the dissolution rates of Pu from the samples prepared by NH4HSO4 fusion declined dramatically from near 100% for 450 °C to 8% for 1000 °C. In contrast, the NH4HF2 fusion was capable of completely releasing Pu from samples that were pre-ignited at temperatures over 450 °C to 1000 °C, which was comparable to releases obtained by the hazardous and time-consuming HNO3-HF digestion, and was superior to the conventional HNO3 digestion. Additionally, because HF is not used in any procedure of the NH4HF2 fusion, a safer and greener alternative to NH4HSO4 fusion and HNO3-HF digestion is realized for rapid Pu determination in environmental samples for nuclear emergency response and application in environmental studies." @default.
- W2899486145 created "2018-11-09" @default.
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- W2899486145 date "2019-03-01" @default.
- W2899486145 modified "2023-10-18" @default.
- W2899486145 title "Low-temperature fusion using NH4HSO4 and NH4HF2 for rapid determination of Pu in soil and sediment samples" @default.
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- W2899486145 doi "https://doi.org/10.1016/j.aca.2018.10.065" @default.
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