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- W2899598257 abstract "The plant secondary cell wall is a complex structure composed of polysaccharides and lignin, and is a key evolutionary innovation of vascular land plants. Although cell wall composition is well understood, the cross-linking of the different polymers is only now yielding to investigation. Cross-linking between hemicelluloses and lignin occurs via two different mechanisms: incorporation into lignin by radical coupling of ferulate substitutions on xylan in commelinid monocots, and incorporation of hemicellulosic glycosyl residues by re-aromatisation of lignification intermediates. Recent genetic evidence indicates that hemicellulose:lignin cross-linking has a substantial impact on plant cell wall recalcitrance. Engineering plant biomass with modified frequencies of cross-links will have significant impacts on biomass utilisation." @default.
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- W2899598257 date "2019-04-01" @default.
- W2899598257 modified "2023-10-03" @default.
- W2899598257 title "Covalent interactions between lignin and hemicelluloses in plant secondary cell walls" @default.
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- W2899598257 doi "https://doi.org/10.1016/j.copbio.2018.10.010" @default.
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