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- W2899609541 abstract "A protocol for three-component reactions of cyclic ethers, α-diazo esters, and weak nitrogen, oxygen, carbon, and sulfur nucleophiles (pKa = 2.2–14.8) to afford a variety of structurally complex α-oxyalkylated esters is reported. These reactions involve intermolecular activation of the cyclic ether (present in excess) by the α-diazo ester to form an oxonium ylide under metal-free conditions, followed by ring opening by the nucleophile." @default.
- W2899609541 created "2018-11-16" @default.
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- W2899609541 date "2018-11-07" @default.
- W2899609541 modified "2023-10-17" @default.
- W2899609541 title "Three-Component Ring-Opening Reactions of Cyclic Ethers, α-Diazo Esters, and Weak Nucleophiles under Metal-Free Conditions" @default.
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- W2899609541 doi "https://doi.org/10.1021/acs.joc.8b02091" @default.
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