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- W2899614904 abstract "Four new β-triketone monoterpene hybrids, intermediones A–D (1–4), have been identified from the flowers of the Australian eucalypt tree Corymbia intermedia. Intermediones A–D are β-triketones that incorporate a pinene moiety attached via a benzyl group to a syncarpic acid. The structures of 1–4, including relative configurations, were elucidated from the analysis of 1D/2D NMR and MS data. The absolute configurations of intermediones A and B were determined by comparison of experimental and predicted ECD spectra. Intermedione D possesses a tetracyclic ring system that is related to that found in the meroterpenes, guadials B and C. Low to moderate antiplasmodial activity toward the chloroquine-sensitive (3D7) strain of Plasmodium falciparum, with IC50 values ranging from 9.9 to 20.8 μM, was observed for intermediones A, B, and D." @default.
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- W2899614904 date "2018-11-06" @default.
- W2899614904 modified "2023-09-24" @default.
- W2899614904 title "β-Triketone–Monoterpene Hybrids from the Flowers of the Australian Tree <i>Corymbia intermedia</i>" @default.
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- W2899614904 doi "https://doi.org/10.1021/acs.jnatprod.8b00494" @default.
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