Matches in SemOpenAlex for { <https://semopenalex.org/work/W2899642259> ?p ?o ?g. }
- W2899642259 endingPage "730" @default.
- W2899642259 startingPage "720" @default.
- W2899642259 abstract "A series of multivalent zwitterionic poly(methacrylate) copolymers (PMGT) containing different reactive ligands (epoxy and –Si–OCH3) are designed and synthesized for surface modification of 3-aminopropyltriethoxysilane activated PDMS (PDMS-A) via a simple incubation and subsequent post-crosslinking procedure. The co-existence of protonated primary amine (NH3+), terminal primary amine (−NH2) and Si–OH/Si–OC2H5 surface receptors on PDMS-A created a platform to fabricate stable PMGT coatings through multivalent interactions with epoxy and –Si–OCH3 ligands in the polymer chains. The effect of molar ratio of epoxy and –Si–(OCH3)3 ligands (ne/nSi) in the polymer chains on the cooperativity of multivalent interactions is studied. The results show that ne/nSi in the PMGT polymer chain plays a crucial role in the regulation of the coating formation. At higher ne/nSi (1.78), a relatively rough and thin biomimetic coating is formed. By contrast, lower ne/nSi (1.04) in the polymer chain is helpful to produce a more uniform and dense polymer coating. It is attributed to the good balance between the anchoring of polymer chains and the growth of coating thickness in the incubation step through suppressing the competitive autocatalytic crosslinking reactions of epoxy-amine system, demonstrating positive cooperativity of multivalent interactions. The following post-crosslinking procedure under moisture atmosphere containing triethylamine (TEA) facilitates to realize the formation of durable PMGT polymer coating, in which zwitterionic PC moieties are orientated towards the outer surface, providing the PDMS with greatly improved controllable hydrophilicity, coating stability and antifouling properties." @default.
- W2899642259 created "2018-11-16" @default.
- W2899642259 creator A5029930125 @default.
- W2899642259 creator A5035446738 @default.
- W2899642259 creator A5045725123 @default.
- W2899642259 creator A5049999335 @default.
- W2899642259 creator A5050810643 @default.
- W2899642259 creator A5066552873 @default.
- W2899642259 creator A5070053244 @default.
- W2899642259 creator A5071335452 @default.
- W2899642259 creator A5082877123 @default.
- W2899642259 date "2019-03-01" @default.
- W2899642259 modified "2023-10-14" @default.
- W2899642259 title "Fabrication of stable biomimetic coating on PDMS surface: Cooperativity of multivalent interactions" @default.
- W2899642259 cites W15140341 @default.
- W2899642259 cites W1966602605 @default.
- W2899642259 cites W1981458454 @default.
- W2899642259 cites W1983331713 @default.
- W2899642259 cites W1987337147 @default.
- W2899642259 cites W1990157378 @default.
- W2899642259 cites W1990675583 @default.
- W2899642259 cites W1993273409 @default.
- W2899642259 cites W2004167273 @default.
- W2899642259 cites W2006779985 @default.
- W2899642259 cites W2008577210 @default.
- W2899642259 cites W2009449936 @default.
- W2899642259 cites W2010828967 @default.
- W2899642259 cites W2015209383 @default.
- W2899642259 cites W2016022695 @default.
- W2899642259 cites W2021623392 @default.
- W2899642259 cites W2026762137 @default.
- W2899642259 cites W2047903920 @default.
- W2899642259 cites W2050005607 @default.
- W2899642259 cites W2076125752 @default.
- W2899642259 cites W2089224580 @default.
- W2899642259 cites W2125909624 @default.
- W2899642259 cites W2126818937 @default.
- W2899642259 cites W2137660694 @default.
- W2899642259 cites W2148284816 @default.
- W2899642259 cites W2164271129 @default.
- W2899642259 cites W2167506924 @default.
- W2899642259 cites W2234833147 @default.
- W2899642259 cites W2300681772 @default.
- W2899642259 cites W2316287488 @default.
- W2899642259 cites W2317148074 @default.
- W2899642259 cites W2319385993 @default.
- W2899642259 cites W2323524544 @default.
- W2899642259 cites W2326276867 @default.
- W2899642259 cites W2329398547 @default.
- W2899642259 cites W2332460075 @default.
- W2899642259 cites W2335675049 @default.
- W2899642259 cites W2417885579 @default.
- W2899642259 cites W2558458794 @default.
- W2899642259 cites W2582433498 @default.
- W2899642259 cites W2590877281 @default.
- W2899642259 cites W2626632165 @default.
- W2899642259 cites W2765362117 @default.
- W2899642259 cites W2766000565 @default.
- W2899642259 cites W2774133161 @default.
- W2899642259 cites W2794636144 @default.
- W2899642259 cites W2797003724 @default.
- W2899642259 cites W2801601836 @default.
- W2899642259 cites W2808243369 @default.
- W2899642259 cites W866630262 @default.
- W2899642259 doi "https://doi.org/10.1016/j.apsusc.2018.11.056" @default.
- W2899642259 hasPublicationYear "2019" @default.
- W2899642259 type Work @default.
- W2899642259 sameAs 2899642259 @default.
- W2899642259 citedByCount "22" @default.
- W2899642259 countsByYear W28996422592019 @default.
- W2899642259 countsByYear W28996422592020 @default.
- W2899642259 countsByYear W28996422592021 @default.
- W2899642259 countsByYear W28996422592022 @default.
- W2899642259 countsByYear W28996422592023 @default.
- W2899642259 crossrefType "journal-article" @default.
- W2899642259 hasAuthorship W2899642259A5029930125 @default.
- W2899642259 hasAuthorship W2899642259A5035446738 @default.
- W2899642259 hasAuthorship W2899642259A5045725123 @default.
- W2899642259 hasAuthorship W2899642259A5049999335 @default.
- W2899642259 hasAuthorship W2899642259A5050810643 @default.
- W2899642259 hasAuthorship W2899642259A5066552873 @default.
- W2899642259 hasAuthorship W2899642259A5070053244 @default.
- W2899642259 hasAuthorship W2899642259A5071335452 @default.
- W2899642259 hasAuthorship W2899642259A5082877123 @default.
- W2899642259 hasConcept C115537861 @default.
- W2899642259 hasConcept C127413603 @default.
- W2899642259 hasConcept C131779359 @default.
- W2899642259 hasConcept C159985019 @default.
- W2899642259 hasConcept C166014724 @default.
- W2899642259 hasConcept C166595027 @default.
- W2899642259 hasConcept C171250308 @default.
- W2899642259 hasConcept C178790620 @default.
- W2899642259 hasConcept C185592680 @default.
- W2899642259 hasConcept C188027245 @default.
- W2899642259 hasConcept C192562407 @default.
- W2899642259 hasConcept C2781448156 @default.
- W2899642259 hasConcept C42360764 @default.
- W2899642259 hasConcept C521977710 @default.