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• W2899648411 endingPage "1465" @default.
• W2899648411 startingPage "1461" @default.
• W2899648411 abstract "The discovery that traditional silver(I)-oxide-promoted glycosidations of glycosyl bromides (Koenigs-Knorr reaction) can be greatly accelerated in the presence of catalytic trimethylsilyl trifluoromethanesulfonate (TMSOTf) is reported. The reaction conditions are very mild that allowed for maintaining a practically neutral pH and, at the same time, providing high rates and excellent glycosylation yields. In addition, unusual reactivity trends among a series of differentially protected glycosyl bromides were documented. In particular, benzoylated α-bromides were much more reactive than their benzylated counterparts under these conditions." @default.
• W2899648411 created "2018-11-16" @default.
• W2899648411 creator A5043089901 @default.
• W2899648411 creator A5089797226 @default.
• W2899648411 date "2018-12-20" @default.
• W2899648411 modified "2023-09-30" @default.
• W2899648411 title "Koenigs–Knorr Glycosylation Reaction Catalyzed by Trimethylsilyl Trifluoromethanesulfonate" @default.
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• W2899648411 doi "https://doi.org/10.1002/chem.201805527" @default.
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