FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2899684559> ?p ?o ?g. }

• W2899684559 endingPage "1223" @default.
• W2899684559 startingPage "1223" @default.
• W2899684559 abstract "The [Rh(L-alaninate)(cod)] (cod = 1,5-Cyclooctadiene) complex was synthesized and characterized. Asymmetric polymerizations of achiral phenylacetylene with two hydroxyl groups and a dodecyl group (DoDHPA) were performed by using the rhodium complex as the catalyst to provide polymers with a higher molecular weight (>105) than the polymers obtained using the [Rh(cod)Cl]2 initiator systems. The resulting polymers showed circular dichroism (CD) signals at approximately 310 and 470 nm, indicating that they have a preferential one-handed helical structure. The helix sense in the polymer main chain was controlled by the sign of the catalyst chirality. These findings suggest that the rhodium complex with a chiral amine is the true active species for the helix-sense-selective polymerization of DoDHPA. The [Rh(L-alaninate)(cod)] complex also exhibits high catalytic activity in the polymerization of phenylacetylene (PA) to give a high yield and molecular weight. All these results demonstrate that this Rh complex is an excellent catalyst for the polymerization of phenylacetylene monomers." @default.
• W2899684559 created "2018-11-16" @default.
• W2899684559 creator A5013244196 @default.
• W2899684559 creator A5025157763 @default.
• W2899684559 creator A5026473517 @default.
• W2899684559 creator A5050607567 @default.
• W2899684559 creator A5055617211 @default.
• W2899684559 creator A5057301071 @default.
• W2899684559 creator A5059333934 @default.
• W2899684559 creator A5061550482 @default.
• W2899684559 creator A5066374381 @default.
• W2899684559 creator A5077871572 @default.
• W2899684559 date "2018-11-03" @default.
• W2899684559 modified "2023-10-05" @default.
• W2899684559 title "[Rh(L-alaninate)(1,5-Cyclooctadiene)] Catalyzed Helix-Sense-Selective Polymerizations of Achiral Phenylacetylenes" @default.
• W2899684559 cites W1969140552 @default.
• W2899684559 cites W1980322334 @default.
• W2899684559 cites W1988786558 @default.
• W2899684559 cites W2012349415 @default.
• W2899684559 cites W2024694153 @default.
• W2899684559 cites W2029502119 @default.
• W2899684559 cites W2030835508 @default.
• W2899684559 cites W2032020845 @default.
• W2899684559 cites W2040312234 @default.
• W2899684559 cites W2042029879 @default.
• W2899684559 cites W2051498016 @default.
• W2899684559 cites W2059860095 @default.
• W2899684559 cites W2062598560 @default.
• W2899684559 cites W2065489777 @default.
• W2899684559 cites W2067459887 @default.
• W2899684559 cites W2080854071 @default.
• W2899684559 cites W2085779700 @default.
• W2899684559 cites W2146420209 @default.
• W2899684559 cites W2285540618 @default.
• W2899684559 cites W2304774177 @default.
• W2899684559 cites W2324932792 @default.
• W2899684559 cites W2327462963 @default.
• W2899684559 cites W2519127617 @default.
• W2899684559 cites W299843295 @default.
• W2899684559 doi "https://doi.org/10.3390/polym10111223" @default.
• W2899684559 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6290612" @default.
• W2899684559 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30961148" @default.
• W2899684559 hasPublicationYear "2018" @default.
• W2899684559 type Work @default.
• W2899684559 sameAs 2899684559 @default.
• W2899684559 citedByCount "4" @default.
• W2899684559 countsByYear W28996845592019 @default.
• W2899684559 countsByYear W28996845592021 @default.
• W2899684559 crossrefType "journal-article" @default.
• W2899684559 hasAuthorship W2899684559A5013244196 @default.
• W2899684559 hasAuthorship W2899684559A5025157763 @default.
• W2899684559 hasAuthorship W2899684559A5026473517 @default.
• W2899684559 hasAuthorship W2899684559A5050607567 @default.
• W2899684559 hasAuthorship W2899684559A5055617211 @default.
• W2899684559 hasAuthorship W2899684559A5057301071 @default.
• W2899684559 hasAuthorship W2899684559A5059333934 @default.
• W2899684559 hasAuthorship W2899684559A5061550482 @default.
• W2899684559 hasAuthorship W2899684559A5066374381 @default.
• W2899684559 hasAuthorship W2899684559A5077871572 @default.
• W2899684559 hasBestOaLocation W28996845591 @default.
• W2899684559 hasConcept C121332964 @default.
• W2899684559 hasConcept C124668440 @default.
• W2899684559 hasConcept C133571119 @default.
• W2899684559 hasConcept C142388413 @default.
• W2899684559 hasConcept C161790260 @default.
• W2899684559 hasConcept C166940927 @default.
• W2899684559 hasConcept C178790620 @default.
• W2899684559 hasConcept C185592680 @default.
• W2899684559 hasConcept C188027245 @default.
• W2899684559 hasConcept C18903297 @default.
• W2899684559 hasConcept C20621625 @default.
• W2899684559 hasConcept C2778530040 @default.
• W2899684559 hasConcept C2778545935 @default.
• W2899684559 hasConcept C2779910884 @default.
• W2899684559 hasConcept C2779965526 @default.
• W2899684559 hasConcept C44228677 @default.
• W2899684559 hasConcept C521398313 @default.
• W2899684559 hasConcept C521977710 @default.
• W2899684559 hasConcept C52703039 @default.
• W2899684559 hasConcept C62520636 @default.
• W2899684559 hasConcept C71240020 @default.
• W2899684559 hasConcept C75473681 @default.
• W2899684559 hasConcept C7602139 @default.
• W2899684559 hasConcept C86803240 @default.
• W2899684559 hasConceptScore W2899684559C121332964 @default.
• W2899684559 hasConceptScore W2899684559C124668440 @default.
• W2899684559 hasConceptScore W2899684559C133571119 @default.
• W2899684559 hasConceptScore W2899684559C142388413 @default.
• W2899684559 hasConceptScore W2899684559C161790260 @default.
• W2899684559 hasConceptScore W2899684559C166940927 @default.
• W2899684559 hasConceptScore W2899684559C178790620 @default.
• W2899684559 hasConceptScore W2899684559C185592680 @default.
• W2899684559 hasConceptScore W2899684559C188027245 @default.
• W2899684559 hasConceptScore W2899684559C18903297 @default.
• W2899684559 hasConceptScore W2899684559C20621625 @default.
• W2899684559 hasConceptScore W2899684559C2778530040 @default.
• W2899684559 hasConceptScore W2899684559C2778545935 @default.
• W2899684559 hasConceptScore W2899684559C2779910884 @default.

• next