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- W2899722900 abstract "Nitrate intercalated hydrotalcite (NO3−-HTC) was first prepared as precursor; a schiff base derivative containing N, P, and S was synthesized and its structure was characterized. Later the schiff base derivative was used as intercalation to replace NO3− in hydrotalcite. The final product was schiff base derivative intercalated hydrotalcite, which was named as benzaldehyde–taurine–hypophosphorous (BTP)-HTC. The results showed both NO3−-HTC and BTP-HTC can effectively improve the flame retardant and thermostability of ethylene vinyl acetate (EVA). In cone calorimeter test, the peak heat release rate of EVA was 1421.2 kW/m2 and reduced sharply to 746.1/584.5 kW/m2 for 20 wt% NO3−-HTC/BTP-HTC adding, respectively. At same time, the total heat release was also decreased from 120.6 MJ/m2 for EVA to 81.0/70.0 MJ/m2, respectively. Morphology observation and composition analysis by scanning electron microscopy (SEM)/X-ray spectroscopy (EDS) documented the residue left after combustion of EVA/NO3−-HTC was just ash containing Mg and Al; but for EVA/BTP-HTC, coherent char layer containing Mg, Al, and P was left. Thermogravimetric analysis indicated that the thermal degradation of EVA was prolonged by either NO3−-HTC or BTP-HTC; and char content was kept to 8.6% and 11.0%, respectively. The whole results documented either NO3−-HTC or BTP-HTC improved the combustion behavior and thermostability of EVA, and BTP-HTC showed excellent effect. J. VINYL ADDIT. TECHNOL., 25:255–261, 2019. © 2018 Society of Plastics Engineers" @default.
- W2899722900 created "2018-11-16" @default.
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- W2899722900 date "2018-11-08" @default.
- W2899722900 modified "2023-10-16" @default.
- W2899722900 title "Fabrication of hydrotalcite containing N/P/S and its ternary synergistic efficiency on thermostability and fire resistance of ethylene vinyl acetate (EVA)" @default.
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- W2899722900 doi "https://doi.org/10.1002/vnl.21684" @default.
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