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• W2899761340 abstract "Abstract Photoinduced reversible intramolecular hydrogen-atom migration between 9H-fluorene and 1H-fluorene isolated in an Ar matrix is found by FTIR spectroscopy with an aid of DFT calculation. The forward isomerization from 9H-fluorene to 1H-fluorene occurs upon UV irradiation (λ ≥ 295 nm), while the backward isomerization occurs upon λ ≥ 320 nm light irradiation. The less stable isomer, 1H-fluorene, is identified by comparison of the measured IR spectrum with the corresponding simulated spectral pattern obtained at the B3LYP/6-31++G(d,p) level. In addition, an IR spectrum of 9H-fluorene in the T1 state is measured during UV irradiation (λ ≥ 275 nm)." @default.
• W2899761340 created "2018-11-16" @default.
• W2899761340 creator A5020109382 @default.
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• W2899761340 date "2019-01-01" @default.
• W2899761340 modified "2023-10-12" @default.
• W2899761340 title "Photoinduced reversible isomerization of 9H-fluorene into 1H-fluorene by means of hydrogen-atom migration and the lowest electronically excited triplet state studied by matrix-isolation FTIR spectroscopy" @default.
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• W2899761340 doi "https://doi.org/10.1016/j.cplett.2018.11.011" @default.
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