Matches in SemOpenAlex for { <https://semopenalex.org/work/W2899797906> ?p ?o ?g. }
- W2899797906 endingPage "15975" @default.
- W2899797906 startingPage "15969" @default.
- W2899797906 abstract "Mechanochromic force probes, including spiropyran derivatives, have proven to be useful in visualizing the stress/strain distribution and fracture behavior in polymeric materials. Here, we report the macroscopic response of silicone elastomers including cross-links made up of three spiropyran (SP) regioisomers. The SP derivatives SP(o), SP(m), and SP(p) are connected to the network through an identical attachment point on the indoline fragment and regioisomeric attachments ortho, meta, and para to the spirocyclic C–O bond on the benzaldehyde fragment, respectively. The relative colorimetric response of these regioisomers under quasi-static uniaxial tensile load is SP(o) > SP(m) > SP(p), consistent with the expected mechanical sensitivity of the regioisomers obtained from molecular modeling. The extrapolated strain onset for detectable activation of all three regioisomers, however, is indistinguishable and occurs at ∼90% uniaxial strain. Finally, the ratiometric response of the three isomers is constant across the strains investigated (90–135% uniaxial strain), in contrast to expectations based on simulations of strained intact polymer networks." @default.
- W2899797906 created "2018-11-16" @default.
- W2899797906 creator A5027052238 @default.
- W2899797906 creator A5040689697 @default.
- W2899797906 creator A5073305222 @default.
- W2899797906 creator A5081394467 @default.
- W2899797906 date "2018-11-07" @default.
- W2899797906 modified "2023-10-16" @default.
- W2899797906 title "Regiochemical Effects on Mechanophore Activation in Bulk Materials" @default.
- W2899797906 cites W105014408 @default.
- W2899797906 cites W1217856046 @default.
- W2899797906 cites W1251317203 @default.
- W2899797906 cites W1732238310 @default.
- W2899797906 cites W1970863842 @default.
- W2899797906 cites W1971215945 @default.
- W2899797906 cites W1980410504 @default.
- W2899797906 cites W1980781458 @default.
- W2899797906 cites W1983551924 @default.
- W2899797906 cites W1996626267 @default.
- W2899797906 cites W2002237790 @default.
- W2899797906 cites W2011943643 @default.
- W2899797906 cites W2023974158 @default.
- W2899797906 cites W2028392752 @default.
- W2899797906 cites W2031035786 @default.
- W2899797906 cites W2034944228 @default.
- W2899797906 cites W2040462201 @default.
- W2899797906 cites W2043008468 @default.
- W2899797906 cites W2044694969 @default.
- W2899797906 cites W2051769448 @default.
- W2899797906 cites W2064004189 @default.
- W2899797906 cites W2075754502 @default.
- W2899797906 cites W2082573532 @default.
- W2899797906 cites W2102344595 @default.
- W2899797906 cites W2119411460 @default.
- W2899797906 cites W2123001063 @default.
- W2899797906 cites W2126501716 @default.
- W2899797906 cites W2129201801 @default.
- W2899797906 cites W2135324828 @default.
- W2899797906 cites W2195295975 @default.
- W2899797906 cites W2197771435 @default.
- W2899797906 cites W2206179108 @default.
- W2899797906 cites W2266031327 @default.
- W2899797906 cites W2313446698 @default.
- W2899797906 cites W2315897910 @default.
- W2899797906 cites W2317669784 @default.
- W2899797906 cites W2320434127 @default.
- W2899797906 cites W2320764839 @default.
- W2899797906 cites W2322102916 @default.
- W2899797906 cites W2322811356 @default.
- W2899797906 cites W2327370759 @default.
- W2899797906 cites W2328417762 @default.
- W2899797906 cites W2415904663 @default.
- W2899797906 cites W2437977100 @default.
- W2899797906 cites W2486848386 @default.
- W2899797906 cites W2498714646 @default.
- W2899797906 cites W2508665891 @default.
- W2899797906 cites W2520129975 @default.
- W2899797906 cites W2584183114 @default.
- W2899797906 cites W2589354359 @default.
- W2899797906 cites W2602323757 @default.
- W2899797906 cites W2603414373 @default.
- W2899797906 cites W2746358053 @default.
- W2899797906 cites W2755528635 @default.
- W2899797906 cites W2766599711 @default.
- W2899797906 cites W2885785398 @default.
- W2899797906 cites W2888092820 @default.
- W2899797906 cites W2888670687 @default.
- W2899797906 cites W2892656212 @default.
- W2899797906 cites W2900187653 @default.
- W2899797906 cites W2952557664 @default.
- W2899797906 doi "https://doi.org/10.1021/jacs.8b10376" @default.
- W2899797906 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30403483" @default.
- W2899797906 hasPublicationYear "2018" @default.
- W2899797906 type Work @default.
- W2899797906 sameAs 2899797906 @default.
- W2899797906 citedByCount "96" @default.
- W2899797906 countsByYear W28997979062018 @default.
- W2899797906 countsByYear W28997979062019 @default.
- W2899797906 countsByYear W28997979062020 @default.
- W2899797906 countsByYear W28997979062021 @default.
- W2899797906 countsByYear W28997979062022 @default.
- W2899797906 countsByYear W28997979062023 @default.
- W2899797906 crossrefType "journal-article" @default.
- W2899797906 hasAuthorship W2899797906A5027052238 @default.
- W2899797906 hasAuthorship W2899797906A5040689697 @default.
- W2899797906 hasAuthorship W2899797906A5073305222 @default.
- W2899797906 hasAuthorship W2899797906A5081394467 @default.
- W2899797906 hasConcept C126322002 @default.
- W2899797906 hasConcept C147597530 @default.
- W2899797906 hasConcept C178790620 @default.
- W2899797906 hasConcept C185592680 @default.
- W2899797906 hasConcept C202235601 @default.
- W2899797906 hasConcept C2778022156 @default.
- W2899797906 hasConcept C2780658000 @default.
- W2899797906 hasConcept C521977710 @default.
- W2899797906 hasConcept C71240020 @default.
- W2899797906 hasConcept C71924100 @default.
- W2899797906 hasConceptScore W2899797906C126322002 @default.