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• W2899829113 abstract "The favorable effect of 2-hydroxyphenyl groups for ketimine formation with benzophenone was demonstrated by combining computational and experimental studies. Although direct imine formation between benzophenone and primary amines is challenging, 2-hydroxybenzophenone or 2,2′-dihydroxybenzophenone was readily used for ketimine formation with various primary alkyl amines and anilines. Measured activation parameters and calculated energy profiles indicated that the 2-hydroxyphenyl group can lower both activation barriers and equilibrium energies by establishing intramolecular and intermolecular hydrogen-bonding interactions." @default.
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• W2899829113 date "2018-11-06" @default.
• W2899829113 modified "2023-10-02" @default.
• W2899829113 title "Hydrogen-Bonding-Assisted Ketimine Formation of Benzophenone Derivatives" @default.
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• W2899829113 doi "https://doi.org/10.1021/acs.joc.8b01908" @default.
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