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- W2900106487 abstract "Abstract In this work we utilize the marked solvatochromism of two cyclodextrin (CD) containing [2]rotaxanes and their CD-free linear precursor in order to investigate preferential solvation (PS) effects in water/ethylene glycol mixtures. Two well-known models of PS are employed in order to quantify the PS and rationalize local solute-solvent and solvent-solvent effects. Structural effects among the solvatochromic probes are furthermore examined in terms of the involvement or not of a CD macrocycle and also in terms of the size of CD involved, between the two [2]rotaxanes." @default.
- W2900106487 created "2018-11-16" @default.
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- W2900106487 date "2019-01-01" @default.
- W2900106487 modified "2023-09-24" @default.
- W2900106487 title "Study of the preferential solvation effects in binary solvent mixtures with the use of intensely solvatochromic azobenzene involving [2]rotaxane solutes" @default.
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- W2900106487 doi "https://doi.org/10.1016/j.molliq.2018.10.164" @default.
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