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- W2900310469 abstract "Here, we present a novel approach for investigating dissolved organic matter (DOM) composition using thermal desorption proton-transfer-reaction mass spectrometry (PTR-MS), a technique that provides insight into the molecular composition of DOM < m/z 500 (termed “PTR-DOC”). The applicability of PTR-MS for understanding the relationship between DOM composition and reactivity has yet to be explored. We present results from a synoptic sampling campaign of streams and lakes in a Swedish forest catchment where we measured DOM composition using PTR-MS and traditional optical methods and conducted DOM biodegradability assays. PTR-DOC comprised ≤12% of the total DOC pool. We found significant relationships between PTR-DOC and DOM degradability; reduced chemodiversity and low concentrations of PTR-DOC were both associated with the total DOM pool being more susceptible to microbial degradation. Furthermore, molecular differences were apparent among headwater lakes, headwater streams, and lakes further down the catc..." @default.
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- W2900310469 date "2018-11-05" @default.
- W2900310469 modified "2023-09-27" @default.
- W2900310469 title "Understanding Dissolved Organic Matter Reactivity and Composition in Lakes and Streams Using Proton-Transfer-Reaction Mass Spectrometry (PTR-MS)" @default.
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- W2900310469 doi "https://doi.org/10.1021/acs.estlett.8b00529" @default.
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