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- W2900366178 abstract "Abstract Biochar is a complex carbonaceous material with numerous physical and chemical parameters that control its reactivity toward inorganic and organic species in aqueous solution. Key to understanding the ways in which solutes will behave toward biochar is the development of models that consider the underlying mechanisms of complexation at the surface of biochar particles. In this chapter, we compare and contrast empirical and theoretical approaches to solute adsorption modeling to biochar. Later, we discuss the development of surface complexation models (SCMs) for biochar, including the collection and modeling of potentiometric titration and solute adsorption data, and how these SCM can be complimented by spectroscopic and calorimetric investigations to constrain the mechanisms of solute binding at biochar functional groups. Finally, we discuss the state of biochar surface chemistry science, including the need for further application of SCM, along with challenges that exist in applying the approach due to the inherent complexity of the material." @default.
- W2900366178 created "2018-11-16" @default.
- W2900366178 creator A5054059516 @default.
- W2900366178 creator A5091552666 @default.
- W2900366178 date "2019-01-01" @default.
- W2900366178 modified "2023-09-23" @default.
- W2900366178 title "Modeling the Surface Chemistry of Biochars" @default.
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- W2900366178 doi "https://doi.org/10.1016/b978-0-12-811729-3.00004-2" @default.
- W2900366178 hasPublicationYear "2019" @default.
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- W2900366178 hasAuthorship W2900366178A5054059516 @default.