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- W2900503577 abstract "Muonium (Mu), an H atom analogue, is employed to probe the addition of free radicals to the P=C bond of a phosphaalkene. Specifically, two unprecedented muoniated free radicals, MesP. -CMu(Me)2 (1 a, minor product) and MesPMu-C. Me2 (1 b, major product), were detected by muon spin spectroscopy (μSR) when a solution of MesP=CMe2 (1: Mes=2,4,6-trimethylphenyl) was exposed to a beam of positive muons (μ+ ). The μ+ serves as a source of Mu (that is, Mu=μ+ +e- ). To confirm the identity of the major product 1 b, its spectral features were compared to its isotopologue, MesPH-C. (Me)CH2 Mu (2 a). Conveniently, 2 a is the sole product of the reaction of MesPH(CMe=CH2 ) (2) with Mu. For all observed radicals, muon, proton, and phosphorus hyperfine coupling constants were determined by μSR and compared to DFT-calculated values." @default.
- W2900503577 created "2018-11-29" @default.
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- W2900503577 date "2018-12-05" @default.
- W2900503577 modified "2023-10-16" @default.
- W2900503577 title "Free Radical Reactivity of a Phosphaalkene Explored Through Studies of Radical Isotopologues" @default.
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- W2900503577 cites W1981993159 @default.
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- W2900503577 cites W2000258456 @default.
- W2900503577 cites W2003375563 @default.
- W2900503577 cites W2010500517 @default.
- W2900503577 cites W2015814840 @default.
- W2900503577 cites W2025828174 @default.
- W2900503577 cites W2027243637 @default.
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- W2900503577 doi "https://doi.org/10.1002/anie.201810967" @default.
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