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• W2900513297 abstract "Three-dimensional (3D) hydrophilic surfaced MMoO4 (M = Ca, Sr and Ba) superstructures were successfully synthesized using a surfactant-assisted hydrothermal route. This green chemistry method by use of inexpensive reagents makes procedure simple and highly reproducible. The prepared materials were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), emission/excitation spectra analyses, and Fourier transform infrared (FT-IR), Raman, and ultraviolet–visible (UV–Vis) spectroscopies. The scanning electron microscope (SEM) studies demonstrated that the optimized material can be synthesized at pH 6 and 180 °C for CaMoO4 and pH 5 and 220 °C for SrMoO4. Prepared materials displayed good dispersion of small-sized gold and the product consisted of a large number of doughnut and sphere-like superstructures for CaMoO4 and SrMoO4, respectively. The result showed that the mean diameters of doughnut and sphere-like particles were about 2.5–5 μm and 2.5 μm, respectively and the as-synthesized self-assembled superstructures were composed of nanosheets with the thickness of about 20–50 nm. Also, the SEM micrographs demonstrate that the morphology of the optimized materials for BaMoO4, synthesised at 200 °C and pH 5, were particles with hierarchical self-assembled architecture that composed of very long central stems with an average length of about 20–40 μm in which perpendicular branches was seen. The luminescence properties of the optimized samples with various morphologies have also been investigated and photoluminescence spectra of the samples showed very obvious red-shifted PL emission without using rare earth ions-doped luminescent materials and the energy transfer process from host to rare earth ions." @default.
• W2900513297 created "2018-11-29" @default.
• W2900513297 creator A5016657516 @default.
• W2900513297 creator A5041465921 @default.
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• W2900513297 date "2019-02-01" @default.
• W2900513297 modified "2023-09-25" @default.
• W2900513297 title "Synthesis of high crystalline hierarchical self-assembled MMoO4 (M=Ca, Sr and Ba) super structures: Having hydrophilic surfaces and obvious red-shifted photoluminescence behavior" @default.
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• W2900513297 doi "https://doi.org/10.1016/j.matchemphys.2018.11.031" @default.
• W2900513297 hasPublicationYear "2019" @default.
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