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- W2900531508 abstract "Organoaluminum derivatives are mostly appreciated for their Lewis acidity properties, but generally not considered as reagents of choice in synthetic transformations involving the creation of C–C bonds. Among these species, dimethylalkynylaluminum reagents represent a special class of compounds, with, in many cases, unique reactivity. This review summarizes the preparation and reactivity of these organometallic reagents with a focus on their synthetic potential. 1 Introduction 2 Preparation of Dimethylalkynylaluminum Reagents 3 Reactivity of Dimethylalkynylaluminum Reagents 3.1 Reactions with Csp3 Electrophiles 3.2 Reactions with Csp2 Electrophiles 4 Transition-Metal-Catalyzed Reactions 4.1 Addition to α,β-Unsaturated Enones 4.2 Coupling Reactions 5 Triple Bond Reactivity 6 Conclusion" @default.
- W2900531508 created "2018-11-29" @default.
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- W2900531508 date "2018-11-20" @default.
- W2900531508 modified "2023-10-12" @default.
- W2900531508 title "Synthesis and Reactivity of Mixed Dimethylalkynylaluminum Reagents" @default.
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- W2900531508 doi "https://doi.org/10.1055/s-0037-1610392" @default.
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