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• W2900532465 abstract "The crystal structure of the title complex (systematic name: trans -aquachlorido{2,2′[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ 4 O , N , N ′, O ′}manganese(III) monohydrate), [Mn(C 16 H 14 N 2 O 2 )Cl(H 2 O)]·H 2 O has been reported previously in the space group P 2 1 / n [Panja et al. (2003). Polyhedron , 22 , 1191–1198]. We obtained the same hydrated complex through an alternative synthesis, and crystallized a new polymorph, in the space group P 2 1 . The molecular conformation of the complex is virtually unmodified, but the absence of the glide plane in the new polymorph halves the unit-cell parameter c , affording a non-centrosymmetric crystal structure with Z = 2, while the previously reported crystal is centrosymmetric with Z = 4. Both phases represent a case of packing polymorphism, similar to other dimorphic crystal structures retrieved from the Cambridge Structural Database." @default.
• W2900532465 created "2018-11-29" @default.
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• W2900532465 date "2018-11-13" @default.
• W2900532465 modified "2023-10-17" @default.
• W2900532465 title "Packing polymorphism in the structure oftrans-aqua[N,N′-bis(salicylidene)ethane-1,2-diamine-κ4O,N,N′,O′]chloridomanganese(III) monohydrate" @default.
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• W2900532465 doi "https://doi.org/10.1107/s2056989018015694" @default.
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