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- W2900599712 abstract "Novel siloxane-containing benzoxazines were prepared from phenol, paraformaldehyde, and bis(p-aminophenoxy)siloxane. The curing reaction of obtained benzoxazines was studied by in-situ Fourier Transform infrared spectroscopy. The curing kinetics and kinetic model were investigated by nonisothermal Differential Scanning Calorimeter. The kinetic data indicated that the activation energy shifted to a higher value with the increase in benzene ring content in benzoxazines, and the siloxane-containing benzoxazines followed an autocatalytic curing model based on Friedman method. Because of the introduction of aminophenoxysiloxane instead of aminopropylsiloxane, the siloxane-containing polybenzoxazines have a higher thermal stability as confirmed by thermogravimetric and pyrolysis analyses, especially for the bis(p-aminophenoxy)diphenylsiloxane-based polybenzoxazine with an initial decomposition temperature of 420 °C and a char yield of 74%." @default.
- W2900599712 created "2018-11-29" @default.
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- W2900599712 date "2019-01-01" @default.
- W2900599712 modified "2023-10-02" @default.
- W2900599712 title "Curing kinetics and thermal stability of novel siloxane-containing benzoxazines" @default.
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- W2900599712 doi "https://doi.org/10.1016/j.tca.2018.11.016" @default.
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