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- W2900643544 abstract "The reactivity of two metal disulfide compounds [MII2(L1SSL1)Cl4] {M = Fe and Co, L1SSL1 = di-2-[bis(2-pyridylmethyl)amino]ethyl disulfide} with dihydrogen peroxide has been investigated. Reaction of the iron(II) disulfide compound [FeII2(L1SSL1)Cl4] with H2O2 results in the formation of the mononuclear iron(III) sulfonate compound [FeIII(L1SO3)Cl2]. The crystal structure combined with EPR spectroscopy confirms that a high-spin (S = 5/2) iron(III) center was generated, which is coordinated by three nitrogen donors and one oxygen atom of the sulfonate group of the tetradentate ligand, and two chloride ions in an octahedral geometry. In contrast, reaction of compound [CoII2(L1SSL1)Cl4] with H2O2 yielded the mononuclear cobalt(III) sulfinate compound [CoIII(L1SO2)Cl2]. The crystal structure and NMR spectroscopy show that in this case a low-spin (S = 0) cobalt(III) center was obtained, which is coordinated by three nitrogen donors and one sulfur atom of the sulfinate group of the tetradentate ligand and two chloride ions in an octahedral geometry." @default.
- W2900643544 created "2018-11-29" @default.
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- W2900643544 date "2018-11-12" @default.
- W2900643544 modified "2023-09-26" @default.
- W2900643544 title "The Reactivity of FeII and CoII Disulfide Compounds with Dihydrogen Peroxide" @default.
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- W2900643544 doi "https://doi.org/10.1002/ejic.201800962" @default.
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