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• W2900743023 endingPage "40984" @default.
• W2900743023 startingPage "40978" @default.
• W2900743023 abstract "Layered Na2/3MnO2 suffers from capacity loss due to Jahn–Teller (J–T) distortion by Mn3+ ions. Herein, density functional theory calculations suggest Na2/3[FexMn1–x]O2 suppresses the J–T effect. The Fe substitution results in a decreased oxygen–metal–oxygen length, leading to decreases in the b and c lattice parameters but an increase in the a lattice constant. As a result, the capacity retention and rate capability are enhanced with an additional redox pair associated with Fe4+/3+. Finally, the thermal properties are improved, with the Fe substitution delaying the exothermic reaction and reducing exothermic heat." @default.
• W2900743023 created "2018-11-29" @default.
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• W2900743023 date "2018-11-15" @default.
• W2900743023 modified "2023-10-16" @default.
• W2900743023 title "Unraveling the Role of Earth-Abundant Fe in the Suppression of Jahn–Teller Distortion of P′2-Type Na_2/3MnO₂: Experimental and Theoretical Studies" @default.
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• W2900743023 doi "https://doi.org/10.1021/acsami.8b16522" @default.
• W2900743023 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30431251" @default.
• W2900743023 hasPublicationYear "2018" @default.
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