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- W2900952048 abstract "The 9,10-dimethyl-9,10-dihydro-9,10-diboraanthracene dianion salt Li2[1] instantaneously reacts with the dichalcogens O2(tBu)2, S2Me2, S2(pTol)2, Se2Ph2, and Te2Ph2 under reductive cleavage of the chalcogen–chalcogen bonds to give lithium chalcogenides and neutral 1. In solution, the products are involved in rapid association/dissociation equilibria. In the crystalline state, 1 and Li[O(tBu)] form a diadduct, whereas Li[SMe] gives a B⋯B-bridged monoadduct. In the three remaining cases, the crystal lattices contain monoadducts of 1 with one tri- and one tetracoordinate boron atom." @default.
- W2900952048 created "2018-11-29" @default.
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- W2900952048 date "2019-01-01" @default.
- W2900952048 modified "2023-09-27" @default.
- W2900952048 title "Chalcogen–chalcogen-bond activation by an ambiphilic, doubly reduced organoborane" @default.
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- W2900952048 doi "https://doi.org/10.1016/j.tet.2018.11.012" @default.
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