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- W2900996976 abstract "The inhibition of Brønsted acid sites by nitrogen-containing molecules was quantified under industrially relevant hydrocracking conditions. This was achieved by testing bifunctional catalysts based on HUSY zeolite in cyclohexane hydroconversion. For ammonia partial pressures within 0.2-2.8 kPa, the percentage of inhibited Brønsted sites was superior to 98% at 623 K. Significant reduction in the ammonia content caused rather moderate variations on the number of available sites. Conversely, a temperature raise from 600 to 640 K triplicated the vacant Brønsted sites due to the significant endothermicity of ammonia desorption. The inhibiting effect of ammonia can be therefore easily modulated by temperature." @default.
- W2900996976 created "2018-11-29" @default.
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- W2900996976 date "2019-03-01" @default.
- W2900996976 modified "2023-09-23" @default.
- W2900996976 title "Quantification of the available acid sites in the hydrocracking of nitrogen-containing feedstocks over USY shaped NiMo-catalysts" @default.
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- W2900996976 doi "https://doi.org/10.1016/j.jiec.2018.11.019" @default.
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