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• W2901029350 abstract "The TBHP/TBAI-mediated synthesis of N-(pyridine-2-yl)amides in water from ketones and 2-aminopyridine via direct oxidative C–C bond cleavage has been developed. A series of ketones, including more challenging inactive aromatic ketones substituted with diverse long-chain alkyl groups, were selectively converted to N-(pyridine-2-yl)amides. Furthermore, the protocol can be applied to aryl alkyl carbinols to afford the corresponding amides in moderate to good yields." @default.
• W2901029350 created "2018-11-29" @default.
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• W2901029350 date "2018-11-19" @default.
• W2901029350 modified "2023-10-16" @default.
• W2901029350 title "Metal-Free Synthesis of <i>N</i>-(Pyridine-2-yl)amides from Ketones via Selective Oxidative Cleavage of C(O)–C(Alkyl) Bond in Water" @default.
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• W2901029350 doi "https://doi.org/10.1021/acs.joc.8b01956" @default.
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