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• W2901079392 abstract "Abstract N‐doped graphene‐like layered carbon (NG) could be synthesized via a metal‐free pyrolysis route from glucose, fructose, and 5‐hydroxymethylfurfural (5‐HMF), which are cheap and widely available biomass or biomass derivatives. A well‐developed thin‐layer structure with large lateral dimensions could be obtained when 5‐HMF was used as the precursor. More importantly, the 5‐HMF‐derived NG gave superior performance in epoxidation reactions compared with the conventional carbon catalysts and the performance of 5‐HMF derived NG was even similar to that of a cobalt catalyst. Characterizations by TEM and XPS accompanied by EPR analysis revealed that the enhanced catalytic properties for NG arise from its high activation ability for both alkenes and O 2 , which are attributed to the graphitic layered structure and graphitic N species, respectively." @default.
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• W2901079392 date "2018-11-21" @default.
• W2901079392 modified "2023-10-17" @default.
• W2901079392 title "Biomass‐Derived Graphene‐like Carbon: Efficient Metal‐Free Carbocatalysts for Epoxidation" @default.
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• W2901079392 doi "https://doi.org/10.1002/anie.201809970" @default.
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