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- W2901284015 abstract "Abstract A tridentate NNO donor Schiff base, 2,4-dichlorido-6-((3-(dimethylamino)propylimino)methyl)phenol (HL) and its three complexes [CdL2]·H2O (1), [NiL2] (2) and [NiLL′(DMF)] (3) (HL′ = 3.5-dichlorosalicylaldehyde) were synthesized and physicochemically characterized by means of elemental analysis, molar conductivity measurements, FT-IR, UV–Vis and NMR spectral studies. The molecular structures of all three complexes were confirmed by X-ray crystallography. In all three complexes, the metal ions are in distorted octahedral environments. [CdL2]·H2O (1) crystallized in a triclinic space group, whereas both [NiL2] (2) and [NiLL′(DMF)] (3) crystallized in the monoclinic crystal system. The crystal structures of the complexes exhibit different types of intermolecular interactions, which have been supported by Hirshfeld surface analysis and associated fingerprint plots. The luminescent properties of the Schiff base and the three complexes were studied, and the nature of the emission was found to be quenching." @default.
- W2901284015 created "2018-11-29" @default.
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- W2901284015 date "2019-01-01" @default.
- W2901284015 modified "2023-09-23" @default.
- W2901284015 title "Cd(II) and Ni(II) complexes from a tridentate NNO Schiff base: Crystal structures, spectral aspects and Hirshfeld surface analysis" @default.
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- W2901284015 doi "https://doi.org/10.1016/j.poly.2018.11.020" @default.
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