FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2901307002> ?p ?o ?g. }

• W2901307002 endingPage "114" @default.
• W2901307002 startingPage "108" @default.
• W2901307002 abstract "The scheelite BaWO4 elaborated by co-precipitation, is a wide band gap semiconductor crystallizing in the tetragonal symmetry. The oxide is identified by X-ray diffraction and characterized by scanning electron microscopy and diffuse reflectance. The optical transition (2.95 eV) involves O2-: 2p orbital and W6+ eg: level, further direct transition occurs at 4.88 eV. The peaks in the Raman spectrum are assigned to symmetrical vibrations of tetragonal units [WO4]2-. The oxide shows an oxygen deficiency and the conductivity follows a thermally activated hopping of lattice polaron with activation energy of 0.31 eV. The photo electrochemical analysis of BaWO4 at pH 5.5 gives a flat band potential of 0.20 VSCE and electrons density of 1.8 × 1019 cm−3. The positive slope of the plot (capacitance−2 - potential) indicates n type conduction, a result confirmed by chrono-amperometry. The frequency dispersion of the real/imaginary impedances is undertaken both in the dark and under illumination; the response is modeled by an equivalent circuit with a predominant bulk contribution. As application, the photo electrons in the conduction band (−0.11 VSCE) reduce oxygen into radicals O2•-, allowing a partial mineralization of ibuprofen, one of the most consumed medicaments. The electro-photocatalysis i.e. combined electrocatalysis/electro-photocatalysis using TiPt as cathode and BaWO4 as anode (100 mA/25 V) shows a high conversion yield (75%), in aerated ibuprofen solution (20 ppm) in less than 6 h under UV light (12 mW cm−2). The reaction follows a pseudo-first order kinetic with a rate constant of 3.7 × 10−3 min−1, about twice higher than that obtained by electrocatalysis (50%, k = 1.9 × 10−3 min−1)." @default.
• W2901307002 created "2018-11-29" @default.
• W2901307002 creator A5027949074 @default.
• W2901307002 creator A5036526422 @default.
• W2901307002 creator A5060529906 @default.
• W2901307002 creator A5072903531 @default.
• W2901307002 date "2019-03-01" @default.
• W2901307002 modified "2023-10-16" @default.
• W2901307002 title "Electrochemical properties of the scheelite BaWO4 prepared by co-precipitation: Application to electro-photocatalysis of ibuprofen degradation" @default.
• W2901307002 cites W1965078878 @default.
• W2901307002 cites W1965621744 @default.
• W2901307002 cites W1968806773 @default.
• W2901307002 cites W1969995379 @default.
• W2901307002 cites W1985255498 @default.
• W2901307002 cites W1990548575 @default.
• W2901307002 cites W2007489119 @default.
• W2901307002 cites W2007771757 @default.
• W2901307002 cites W2008953182 @default.
• W2901307002 cites W2009877492 @default.
• W2901307002 cites W2014866342 @default.
• W2901307002 cites W2018426844 @default.
• W2901307002 cites W2022622245 @default.
• W2901307002 cites W2025393365 @default.
• W2901307002 cites W2025756637 @default.
• W2901307002 cites W2038452505 @default.
• W2901307002 cites W2052505833 @default.
• W2901307002 cites W2057945372 @default.
• W2901307002 cites W2066316612 @default.
• W2901307002 cites W2067533429 @default.
• W2901307002 cites W2068324382 @default.
• W2901307002 cites W2068930108 @default.
• W2901307002 cites W2075800969 @default.
• W2901307002 cites W2078591996 @default.
• W2901307002 cites W2081629957 @default.
• W2901307002 cites W2085377380 @default.
• W2901307002 cites W2095028189 @default.
• W2901307002 cites W2097359341 @default.
• W2901307002 cites W2462266811 @default.
• W2901307002 cites W2521514894 @default.
• W2901307002 cites W2608957838 @default.
• W2901307002 cites W2750782584 @default.
• W2901307002 cites W2809545330 @default.
• W2901307002 cites W849547810 @default.
• W2901307002 cites W2470220711 @default.
• W2901307002 doi "https://doi.org/10.1016/j.mssp.2018.11.017" @default.
• W2901307002 hasPublicationYear "2019" @default.
• W2901307002 type Work @default.
• W2901307002 sameAs 2901307002 @default.
• W2901307002 citedByCount "25" @default.
• W2901307002 countsByYear W29013070022019 @default.
• W2901307002 countsByYear W29013070022020 @default.
• W2901307002 countsByYear W29013070022021 @default.
• W2901307002 countsByYear W29013070022022 @default.
• W2901307002 countsByYear W29013070022023 @default.
• W2901307002 crossrefType "journal-article" @default.
• W2901307002 hasAuthorship W2901307002A5027949074 @default.
• W2901307002 hasAuthorship W2901307002A5036526422 @default.
• W2901307002 hasAuthorship W2901307002A5060529906 @default.
• W2901307002 hasAuthorship W2901307002A5072903531 @default.
• W2901307002 hasConcept C113196181 @default.
• W2901307002 hasConcept C161790260 @default.
• W2901307002 hasConcept C181966813 @default.
• W2901307002 hasConcept C185592680 @default.
• W2901307002 hasConcept C191897082 @default.
• W2901307002 hasConcept C192562407 @default.
• W2901307002 hasConcept C2779851234 @default.
• W2901307002 hasConcept C43617362 @default.
• W2901307002 hasConcept C49040817 @default.
• W2901307002 hasConcept C55493867 @default.
• W2901307002 hasConcept C65165184 @default.
• W2901307002 hasConceptScore W2901307002C113196181 @default.
• W2901307002 hasConceptScore W2901307002C161790260 @default.
• W2901307002 hasConceptScore W2901307002C181966813 @default.
• W2901307002 hasConceptScore W2901307002C185592680 @default.
• W2901307002 hasConceptScore W2901307002C191897082 @default.
• W2901307002 hasConceptScore W2901307002C192562407 @default.
• W2901307002 hasConceptScore W2901307002C2779851234 @default.
• W2901307002 hasConceptScore W2901307002C43617362 @default.
• W2901307002 hasConceptScore W2901307002C49040817 @default.
• W2901307002 hasConceptScore W2901307002C55493867 @default.
• W2901307002 hasConceptScore W2901307002C65165184 @default.
• W2901307002 hasLocation W29013070021 @default.
• W2901307002 hasOpenAccess W2901307002 @default.
• W2901307002 hasPrimaryLocation W29013070021 @default.
• W2901307002 hasRelatedWork W1631806799 @default.
• W2901307002 hasRelatedWork W2020946050 @default.
• W2901307002 hasRelatedWork W2124282911 @default.
• W2901307002 hasRelatedWork W2134948224 @default.
• W2901307002 hasRelatedWork W2321720038 @default.
• W2901307002 hasRelatedWork W2414885887 @default.
• W2901307002 hasRelatedWork W2550273502 @default.
• W2901307002 hasRelatedWork W2563097281 @default.
• W2901307002 hasRelatedWork W2749294485 @default.
• W2901307002 hasRelatedWork W2794874834 @default.
• W2901307002 hasVolume "91" @default.
• W2901307002 isParatext "false" @default.
• W2901307002 isRetracted "false" @default.
• W2901307002 magId "2901307002" @default.

• next