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- W2901445654 abstract "Doping with halide ions is a popular method to alter the properties of metal phthalocyanines (MPcs), particularly magnetic and electrical nature of organic semiconductors for applications in spintronic or electronic devices. Doping can cause a structural rearrangement in MPc packing, and the physical properties may be correlated with molecular packing. Films of a planar and magnetic MPc, manganese(II)phthalocyanine (MnPc), are chosen for iodine doping study. The optical, magnetic, and electrical properties of pristine- and iodine-doped MnPc thin films are investigated and can be directly associated with their molecular structure. Two-dimensional grazing incidence synchrotron X-ray diffraction reveals structural disorder in MnPc films upon iodine infusion induced by the reorientation of ordered, edge-on molecular configuration to tilted and face-on configurations in a random fashion. The film morphology changes accordingly, where in the uniform crystallites reorganize in a disordered manner. The ferromagnetic nature of the pristine film gets weakened because of iodine species and favors antiferromagnetic coupling. The study of electrical properties at room temperature by conducting atomic force microscopy reveals that the conductance is enhanced independently of the film thickness because of the disorder induced by iodine inclusion." @default.
- W2901445654 created "2018-11-29" @default.
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- W2901445654 date "2018-11-19" @default.
- W2901445654 modified "2023-09-27" @default.
- W2901445654 title "Influence of Iodine Doping on the Structure, Morphology, and Physical Properties of Manganese Phthalocyanine Thin Films" @default.
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- W2901445654 doi "https://doi.org/10.1021/acs.jpcc.8b08205" @default.
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