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• W2901467075 abstract "Starting from isoquinolones, the cis-selective annulation of six-membered rings was possible employing cyclobutenes as olefin components in a [2 + 2] photocycloaddition–fragmentation approach (nine examples, 54–80% yield). The developed sequence enables a conceptually new entry to cis-fused lycorine-type alkaloids of the Amaryllidaceae family with the complete carbon skeleton being successfully assembled. A subsequent von Braun-type reaction emphasized the biological relation between lycorine- and homolycorine-type alkaloids providing a synthetic tool to access this class of natural products." @default.
• W2901467075 created "2018-11-29" @default.
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• W2901467075 date "2018-11-20" @default.
• W2901467075 modified "2023-09-24" @default.
• W2901467075 title "A [2 + 2] Photocycloaddition–Fragmentation Approach toward the Carbon Skeleton of <i>cis</i>-Fused Lycorine-type Alkaloids" @default.
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• W2901467075 doi "https://doi.org/10.1021/acs.orglett.8b03402" @default.
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