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- W2901471337 abstract "Herein, metal-free radical Heck-type reaction of styrenes with sulfonyl hydrazides to synthesize vinyl sulfones is developed. The reaction is performed under economical TBAI/TBHP system on water in open air at room temperature, which proceeds through the radical addition to styrenes followed by hydrogen-abstraction. When compared to known approaches for the synthesis of vinyl sulfones from alkenes, this radical Heck-type strategy is practical, green and does not go through HI elimination process. Furthermore, this protocol can be expanded to the iodosulfonylation of alkynes for the synthesis of iodovinyl sulfones." @default.
- W2901471337 created "2018-11-29" @default.
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- W2901471337 date "2019-01-01" @default.
- W2901471337 modified "2023-10-15" @default.
- W2901471337 title "Radical Heck-type reaction of styrenes with sulfonyl hydrazides on water at room temperature" @default.
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- W2901471337 doi "https://doi.org/10.1016/j.tetlet.2018.11.059" @default.
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