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- W2901545500 abstract "The ν2 and ν5 fundamental bands of thionyl chloride (SOCl2) were measured in the 420 cm−1–550 cm−1 region using the FT-far-IR spectrometer exploiting synchrotron radiation on the AILES beamline at SOLEIL. A straightforward line-by-line analysis is complicated by the high congestion of the spectrum due to both the high density of SOCl2 rovibrational bands and the presence of the ν2 fundamental band of sulfur dioxide produced by hydrolysis of SOCl2 with residual water. To overcome this difficulty, our assignment procedure for the main isotopologues 32S16O35Cl2 and 32S16O35Cl37Cl alternates between a direct fit of the spectrum, via a global optimization technique, and a traditional line-by-line analysis. The global optimization, based on an evolutionary algorithm, produces rotational constants and band centers that serve as useful starting values for the subsequent spectroscopic analysis. This work helped to identify the pure rotational submillimeter spectrum of 32S16O35Cl2 in the v2=1 and v5=1 vibrational s..." @default.
- W2901545500 created "2018-11-29" @default.
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- W2901545500 date "2018-06-20" @default.
- W2901545500 modified "2023-09-25" @default.
- W2901545500 title "HIGH RESOLUTION STUDY OF THE ν2 AND ν5 ROVIBRATIONAL FUNDAMENTAL BANDS OF THIONYL CHLORIDE : INTERPLAY OF AN EVOLUTIONARY ALGORITHM AND A LINE-BY-LINE ANALYSIS" @default.
- W2901545500 doi "https://doi.org/10.15278/isms.2018.wc03" @default.
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