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- W2901554368 abstract "Abstract A series of metallosupramolecular architectures have been prepared, including rectangles, prisms and cages, that feature half‐sandwich rhodium(III) fragments at the vertices. Remarkably, a stable cage‐like heteropolymetallic complex possessing eight rhodium(III) and two silver(I) metal ions ( 3 ) has been obtained following a multistep procedure. The Rh III /Ag I mixed macrocage enables the separation of dihalogenated benzene derivatives with high selectivity. Furthermore, a detailed X‐ray crystallographic study confirmed that the discriminative encapsulation of para ‐dihalobenzene (dichlorobenzene, dibromobenzene and diiodobenzene) is favored by Ag‐π interactions and steric effects." @default.
- W2901554368 created "2018-11-29" @default.
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- W2901554368 creator A5088250941 @default.
- W2901554368 date "2018-12-06" @default.
- W2901554368 modified "2023-09-26" @default.
- W2901554368 title "Selective Encapsulation and Separation of Dihalobenzene Isomers with Discrete Heterometallic Macrocages" @default.
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- W2901554368 doi "https://doi.org/10.1002/chem.201805383" @default.
- W2901554368 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30430671" @default.
- W2901554368 hasPublicationYear "2018" @default.
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