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- W2901606026 endingPage "15086" @default.
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- W2901606026 abstract "We have investigated both batch and continuous flow photoarylations of enol-acetates to yield different α-arylated aldehyde and ketone building blocks by using diazonium salts as the aryl-radical source. Different porphyrins were used as SET photocatalysts, and photophysical as well as electrochemical studies were performed to rationalize the photoredox properties and suggest mechanistic insights. Notably, the most electron-deficient porphyrin ( meso-tetra(pentafluorophenyl)porphyrin) shows the best photoactivity as an electron donor in the triplet excited state, which was rationalized by the redox potentials of excited states and the turnover of the porphyrins in the photocatalytic cycle. A two-step continuous protocol and multigram-scale reactions are also presented revealing a robust, cost-competitive, and easy methodology, highlighting the significant potential of porphyrins as SET photocatalysts." @default.
- W2901606026 created "2018-11-29" @default.
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- W2901606026 date "2018-11-20" @default.
- W2901606026 modified "2023-10-16" @default.
- W2901606026 title "Porphyrins as Photoredox Catalysts in Csp<sup>2</sup>–H Arylations: Batch and Continuous Flow Approaches" @default.
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- W2901606026 cites W1979992077 @default.
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- W2901606026 cites W1996941025 @default.
- W2901606026 cites W2001730903 @default.
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- W2901606026 doi "https://doi.org/10.1021/acs.joc.8b02355" @default.
- W2901606026 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30456953" @default.
- W2901606026 hasPublicationYear "2018" @default.
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