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• W2901676821 abstract "We have developed a direct method for the synthesis of cis-substituted cyclopropanes from a cyclopropanecarboxamide through stereocontrolled metalation and Negishi coupling. Under the optimized reaction conditions, various substituents, including di/trisubstituted alkenes and aryl groups, were introduced in a stereoselective manner using a simple amide directing group that could subsequently be converted into an ester. Furthermore, this method was applicable to the synthesis of all-cis-substituted cyclopropanes bearing three different substituents, which are highly congested and strained molecules." @default.
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• W2901676821 date "2018-11-21" @default.
• W2901676821 modified "2023-10-08" @default.
• W2901676821 title "Synthesis of <i>cis</i>-/All-<i>cis</i>-Substituted Cyclopropanes through Stereocontrolled Metalation and Pd-Catalyzed Negishi Coupling" @default.
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• W2901676821 doi "https://doi.org/10.1021/acs.orglett.8b03390" @default.
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