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- W2901714618 abstract "A review of recent advances of the chemistry of polyhalogenaromaticcompounds, with an emphasis placed on the uses of the corresponding lithiumand Grignard derivatives in the formation of polyhalogenaromatic complexesof metals and metalloids is presented.1,2,3-Tribromotrifluorobenzene was prepared by the decomposition of 1-lithio-2-bromotetrafluorobenzene in the presence of dry lithium bromide, and itsstructure elucidated from 19F and 13C nuclear magnetic resonance studies.Mass spectral analysis of the reaction products showed the presence of1,2,3,4-tetrabromodifluorobenzene, formed by further attack of n-butyllithiumon the tri-bromo-derivative with subsequent decomposition in the presence oflithium bromide. Polybromobiphenyls, having molecular formulae C12F7Br3 andC12F6Br4 were detected in the reaction products by mass spectrometry andmechanisms are given to account for their formation. [Continues.]" @default.
- W2901714618 created "2018-11-29" @default.
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- W2901714618 date "1976-01-01" @default.
- W2901714618 modified "2023-09-24" @default.
- W2901714618 title "Some studies in perhaloaromatic chemistry" @default.
- W2901714618 hasPublicationYear "1976" @default.
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