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- W2901808119 abstract "A new model material of Na0.6[Mg(II)0.3Mn(IV)0.7]O2, with only Mg2+ and Mn4+ in the transition metal layers, is synthesized for the research of anionic redox reaction. The material delivers a capacity of ∼130 mAh/g with a long plateau at ∼4.2 V in the initial charge profile, indicating anionic redox reaction (ARR) involved during the initial desodiation process. In the following cycles, the reversible capacity can reach a high value of ∼210 mAh/g, which is probably derived from the participation of both ARR and Mn3+/Mn4+ redox couples, further proving the charge compensation from ARR during the initial charge and following cycles. The designed cathode material without Mn3+ helps avoid the influence of oxygen activity from transition metals, enabling the investigation of ARR without other distractions." @default.
- W2901808119 created "2018-11-29" @default.
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- W2901808119 date "2018-12-01" @default.
- W2901808119 modified "2023-09-27" @default.
- W2901808119 title "P2-type Na0.6[Mg(II)0.3Mn(IV)0.7]O2 as a new model material for anionic redox reaction" @default.
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- W2901808119 doi "https://doi.org/10.1016/j.cclet.2018.11.023" @default.
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