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- W2901827219 abstract "The acidity ladder scale in [BMPY][NTf2] was successfully expanded toward the weak acidity region for about five more pK units compared to the previously established one. This allows the acidities of a series of 13 aliphatic and aromatic nitroalkanes to be determined accurately by the UV–vis spectroscopic method. The acidity of nitroalkane in [BMPY][NTf2] covers ∼8 pK units and is significantly weaker than those in DMSO and water. The Hammett plot for 4-substituted phenylnitromethanes shows an excellent linearity with a slope of 2.06, which is rather close to that in DMSO but significantly larger than that in water (0.80). The regression analyses reveal that the solvation behavior of [BMPY][NTf2] on the acidic dissociations of C–H acids is similar to that of DMSO." @default.
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- W2901827219 date "2018-11-16" @default.
- W2901827219 modified "2023-10-16" @default.
- W2901827219 title "Equilibrium Acidities of Nitroalkanes in an Ionic Liquid" @default.
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- W2901827219 doi "https://doi.org/10.1021/acs.joc.8b02183" @default.
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