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- W2901888185 abstract "This contribution deals with the synthesis and utilization of a new pyrazole-based unsymmetrical ligand, 3-(3-carboxyphenyl)-1H-pyrazole-5-carboxylic acid (H2CPCA), for generating multifunctional materials. The reaction with the Co(II) salt in the presence of a co-ligand 2,9-dimethyl phenanthroline (dmphen) results in the formation of the helical compound {[Co2(dmphen)2(CPCA)2]DMF}n (1). However, two isostructural monomeric complexes are formed {[M(HCPCA)2(H2O)2], M = Co(II), (2) and Mn(II) (3)} when reactions were carried out in the absence of dmphen. Compound 1 shows some highly encouraging single-ion magnetic (SIM) properties. Detailed magnetic studies unveil slow relaxation of magnetization of compound 1, driven by the higher magnetic anisotropy of the cobalt ion, with the energy barrier of ∼9.2 K and relaxation time of 9.1 × 10–5 s, suggesting a SIM behavior. Moreover, UV–vis and fluorescence studies confirm the selective dye degradation of compound 1 with methylene blue both in the presence and absence of H2O2, with the remarkable degradation efficiency of ∼98 and ∼82%, respectively." @default.
- W2901888185 created "2018-11-29" @default.
- W2901888185 creator A5000947943 @default.
- W2901888185 creator A5003013220 @default.
- W2901888185 creator A5040789519 @default.
- W2901888185 creator A5072343015 @default.
- W2901888185 date "2018-11-12" @default.
- W2901888185 modified "2023-09-29" @default.
- W2901888185 title "Multifunctional Properties of a 1D Helical Co(II) Coordination Polymer: Toward Single-Ion Magnetic Behavior and Efficient Dye Degradation" @default.
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- W2901888185 doi "https://doi.org/10.1021/acsomega.8b02212" @default.
- W2901888185 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6644332" @default.
- W2901888185 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31458193" @default.
- W2901888185 hasPublicationYear "2018" @default.
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