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• W2902016002 abstract "The reaction cavity of the nitro group in the crystal of the title compound, [CoCl(NO 2 )(C 10 H 24 N 4 )]Cl, (I), was investigated to confirm that it offers sufficient free space for linkage isomerization to occur in accordance with the observed photochemical reactivity. The complex cation has crystallographic 2/ m symmetry and the nitro and chloro ligands at the trans positions are statistically disordered. The complete cyclam ligand is generated by symmetry from a quarter of the molecule. In the crystal of (I), the complex cations and Cl − ions are linked into a three-dimensional network by N—H...Cl(counter-ion) hydrogen bonds." @default.
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• W2902016002 date "2018-11-30" @default.
• W2902016002 modified "2023-10-05" @default.
• W2902016002 title "Investigation of nitro–nitrito photoisomerization: crystal structure of<i>trans</i>-chloridonitro(1,4,8,11-tetraazacyclotetradecane-κ⁴<i>N</i>,<i>N</i>′,<i>N</i>′′,<i>N</i>′′′)cobalt(III) chloride" @default.
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• W2902016002 doi "https://doi.org/10.1107/s205698901801678x" @default.
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