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- W2902036009 endingPage "7730" @default.
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- W2902036009 abstract "N-Methylated amino acids and peptides with an 8-aminoquinoline (AQ) directing group can be subjected to stereoselective Pd-catalyzed β-functionalizations. The best results are obtained with aryl iodides, but alkyl and alkenyl side chains can also be introduced. The AQ protecting group can easily be removed, providing the free carboxylic acid, which can be used directly in peptide couplings. This protocol was used successfully as a key step in the synthesis of the cyclopeptide alkaloids abyssenine A and mucronine E." @default.
- W2902036009 created "2018-12-11" @default.
- W2902036009 creator A5087346940 @default.
- W2902036009 creator A5088253534 @default.
- W2902036009 date "2018-11-26" @default.
- W2902036009 modified "2023-09-25" @default.
- W2902036009 title "C–H Functionalization of <i>N</i>-Methylated Amino Acids and Peptides as Tool in Natural Product Synthesis: Synthesis of Abyssenine A and Mucronine E" @default.
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- W2902036009 doi "https://doi.org/10.1021/acs.orglett.8b03475" @default.
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