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• W2902059467 abstract "This article reports the first example of a 2-pyridone accelerated non-directed C-H cyanation with an arene as the limiting reagent. This protocol is compatible with a broad scope of arenes, including advanced intermediates, drug molecules, and natural products. A kinetic isotope experiment (kH /kD =4.40) indicates that the C-H bond cleavage is the rate-limiting step. Also, the reaction is readily scalable, further showcasing the synthetic utility of this method." @default.
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• W2902059467 date "2019-01-16" @default.
• W2902059467 modified "2023-09-24" @default.
• W2902059467 title "Ligand-Promoted Non-Directed C−H Cyanation of Arenes" @default.
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• W2902059467 doi "https://doi.org/10.1002/chem.201805772" @default.
• W2902059467 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6599606" @default.
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