Matches in SemOpenAlex for { <https://semopenalex.org/work/W2902088386> ?p ?o ?g. }
- W2902088386 endingPage "81" @default.
- W2902088386 startingPage "73" @default.
- W2902088386 abstract "Hydrated singly charged metal ions doped with carbon dioxide, Mg2+(CO2)-(H2O) n, in the gas phase are valuable model systems for the electrochemical activation of CO2. Here, we study these systems by Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry combined with ab initio calculations. We show that the exchange reaction of CO2 with O2 proceeds fast with bare Mg+(CO2), with a rate coefficient kabs = 1.2 × 10-10 cm3 s-1, while hydrated species exhibit a lower rate in the range of kabs = (1.2-2.4) × 10-11 cm3 s-1 for this strongly exothermic reaction. Water makes the exchange reaction more exothermic but, at the same time, considerably slower. The results are rationalized with a need for proper orientation of the reactants in the hydrated system, with formation of a Mg2+(CO4)-(H2O) n intermediate while the activation energy is negligible. According to our nanocalorimetric analysis, the exchange reaction of the hydrated ion is exothermic by -1.7 ± 0.5 eV, in agreement with quantum chemical calculations." @default.
- W2902088386 created "2018-12-11" @default.
- W2902088386 creator A5010482554 @default.
- W2902088386 creator A5020851689 @default.
- W2902088386 creator A5042872861 @default.
- W2902088386 creator A5059768180 @default.
- W2902088386 creator A5068279513 @default.
- W2902088386 creator A5069156894 @default.
- W2902088386 date "2018-12-05" @default.
- W2902088386 modified "2023-10-17" @default.
- W2902088386 title "CO<sub>2</sub>/O<sub>2</sub> Exchange in Magnesium–Water Clusters Mg<sup>+</sup>(H<sub>2</sub>O)<i><sub>n</sub></i>" @default.
- W2902088386 cites W1561059585 @default.
- W2902088386 cites W1801447479 @default.
- W2902088386 cites W1964151435 @default.
- W2902088386 cites W1964152392 @default.
- W2902088386 cites W1966817137 @default.
- W2902088386 cites W1968909145 @default.
- W2902088386 cites W1969173287 @default.
- W2902088386 cites W1970131847 @default.
- W2902088386 cites W1970890810 @default.
- W2902088386 cites W1971983473 @default.
- W2902088386 cites W1974213706 @default.
- W2902088386 cites W1977548474 @default.
- W2902088386 cites W1981845529 @default.
- W2902088386 cites W1984028404 @default.
- W2902088386 cites W1984275719 @default.
- W2902088386 cites W1985912564 @default.
- W2902088386 cites W1990405386 @default.
- W2902088386 cites W1991254332 @default.
- W2902088386 cites W1991365148 @default.
- W2902088386 cites W1993614666 @default.
- W2902088386 cites W1993718641 @default.
- W2902088386 cites W1994424117 @default.
- W2902088386 cites W2005327299 @default.
- W2902088386 cites W2007528714 @default.
- W2902088386 cites W2007968374 @default.
- W2902088386 cites W2012216630 @default.
- W2902088386 cites W2016092523 @default.
- W2902088386 cites W2020017439 @default.
- W2902088386 cites W2021555448 @default.
- W2902088386 cites W2021657648 @default.
- W2902088386 cites W2025112400 @default.
- W2902088386 cites W2026212244 @default.
- W2902088386 cites W2027157035 @default.
- W2902088386 cites W2029322659 @default.
- W2902088386 cites W2033291930 @default.
- W2902088386 cites W2035177899 @default.
- W2902088386 cites W2037956009 @default.
- W2902088386 cites W2038003118 @default.
- W2902088386 cites W2039179398 @default.
- W2902088386 cites W2045242826 @default.
- W2902088386 cites W2046863894 @default.
- W2902088386 cites W2047554875 @default.
- W2902088386 cites W2049822504 @default.
- W2902088386 cites W2050056108 @default.
- W2902088386 cites W2056491666 @default.
- W2902088386 cites W2060370070 @default.
- W2902088386 cites W2065566536 @default.
- W2902088386 cites W2069031182 @default.
- W2902088386 cites W2069438435 @default.
- W2902088386 cites W2071752343 @default.
- W2902088386 cites W2071940095 @default.
- W2902088386 cites W2076283484 @default.
- W2902088386 cites W2086505034 @default.
- W2902088386 cites W2087361743 @default.
- W2902088386 cites W2088459815 @default.
- W2902088386 cites W2089457306 @default.
- W2902088386 cites W2090234051 @default.
- W2902088386 cites W2095275895 @default.
- W2902088386 cites W2108915449 @default.
- W2902088386 cites W2122429100 @default.
- W2902088386 cites W2124666807 @default.
- W2902088386 cites W2134977717 @default.
- W2902088386 cites W2134986692 @default.
- W2902088386 cites W2139095447 @default.
- W2902088386 cites W2150697053 @default.
- W2902088386 cites W2151334055 @default.
- W2902088386 cites W2158052674 @default.
- W2902088386 cites W2166239192 @default.
- W2902088386 cites W2168805475 @default.
- W2902088386 cites W2172318400 @default.
- W2902088386 cites W2313733831 @default.
- W2902088386 cites W2324215383 @default.
- W2902088386 cites W2325573850 @default.
- W2902088386 cites W2326849530 @default.
- W2902088386 cites W2331022453 @default.
- W2902088386 cites W2331522117 @default.
- W2902088386 cites W2334595773 @default.
- W2902088386 cites W2337796977 @default.
- W2902088386 cites W2412269742 @default.
- W2902088386 cites W2487014343 @default.
- W2902088386 cites W2736915708 @default.
- W2902088386 cites W2788631119 @default.
- W2902088386 cites W2792028997 @default.
- W2902088386 cites W2795701534 @default.
- W2902088386 cites W2883751785 @default.
- W2902088386 cites W2897598626 @default.
- W2902088386 cites W2951470060 @default.